Please use this identifier to cite or link to this item: http://hdl.handle.net/123456789/1899
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dc.contributor.authorChattopadhyay, Anwita-
dc.date.accessioned2022-12-16T07:11:06Z-
dc.date.available2022-12-16T07:11:06Z-
dc.date.issued2022-04-
dc.identifier.urihttp://hdl.handle.net/123456789/1899-
dc.description.abstractUtilizing the unique characteristics of the sulfoxonium ylides to undergo bi-functionalization reactions, our group has developed several unusual and proficient cyclopropanation strategies to access several highly functionalized and synthetically privileged motifs in single step from easy-to-prepare starting compounds. Subsequently, we planned to extend the scope of these methodologies. Hence, we have investigated the reactivity of sulfoxonium ylides with biaryl enone-aldehyde substrates, as this chemistry with sulfoxonium ylides is yet unexplored with biaryl scaffolds. It has been found that reaction of dioxosulfoxonium methylide (DOSM) with designed biaryl substrates deliver a series of cyclopropa-fused dibenzocycloheptanoid scaffolds in excellent yields. Dibenzocycloheptanoids represent the core of several bioactive natural products.en_US
dc.language.isoen_USen_US
dc.publisherIISER Mohalien_US
dc.subjectUnusual Reactionsen_US
dc.subjectCorey-Chaykovskyen_US
dc.subjectFused Dibenzocycloheptanoidsen_US
dc.titleUnusual Reactions Mediated by the Corey-Chaykovsky Reagent to Synthesize Cyclopropa-Fused Dibenzocycloheptanoidsen_US
dc.typeThesisen_US
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