Please use this identifier to cite or link to this item: http://hdl.handle.net/123456789/1688
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dc.contributor.authorV., Sreelakshmi-
dc.contributor.authorVenkataramani, Sugumar-
dc.date.accessioned2021-12-10T19:26:03Z-
dc.date.available2021-12-10T19:26:03Z-
dc.date.issued2021-07-28-
dc.identifier.urihttp://hdl.handle.net/123456789/1688-
dc.description.abstractThe discovery of azoheteroarene based photoswitches has increased the stability of Z isomer and showed better photoswitching. Another remarkable fact is applications of C 3 symmetric systems in supramolecular chemistry, where structures like fibers, gels, solid spheres find applications in daily life. Herein, we present tri-substituted triazine core with isoxazole-based photoswitches with varying the linker such as amine, and ether. Three triazine-based tripodal systems were successfully synthesized. Their characteristaion is done with 1 H and 13 C NMR spectroscopy, photophysical studies including forward, reverse isomerisation and kinetic studies are done with the help of UV-Vis spectroscopy. These tripodal systems show good photoconversions and longer half-lives of photoswitched states. Due to the presence of aromatic moiety, some of the reported molecules show aggregation property, which we tried to understand with the help of UV-Vis spectroscopic and DLS techniques. The photoswitching property of certain molecules have been hindered at high concentration due to excessive aggregation caused by these supramolecular interactions.en_US
dc.language.isoen_USen_US
dc.publisherIISERMen_US
dc.subjectPhotoswitching Studiesen_US
dc.subjectC 3 -symmetric PhotoswitchableTripodal Systemsen_US
dc.titleDesign, Synthesis, Characterization and Photoswitching Studies of C 3 -symmetric Photoswitchable Tripodal Systemsen_US
dc.typeThesisen_US
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